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KMID : 1059519840280040265
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Journal of the Korean Chemical Society
1984 Volume.28 No. 4 p.265 ~ p.268
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Kinetics and Mechanism for Reactions of Substituted Phenacyl Bromides with Quinoline
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Kim Chang-Suk
Hong Soon-Yung
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Abstract
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Rates of reactions of nine m-or p-substituted phenacyl bromides with quinoline in methanol were measured by an electric conductivity method. These reactions were found to proceed through an SN2 path and were accelerated by both electron-donating and electron-withdrawing substituents. A plausible reaction mechanism for this observation was proposed. Some activation parameters for these reactions were also calculated.
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